کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1523629 | 1511828 | 2012 | 7 صفحه PDF | دانلود رایگان |

Phase diagram of the ternary Ni–Sb–Zn system was investigated experimentally by DSC and SEM-EDS methods and theoretically by the CALPHAD method. The liquidus projection, invariant equilibria, several vertical sections and isothermal sections at 600 °C and 25 °C were predicted using COST MP0602 thermodynamic database. Phase transition temperatures of alloys along three predicted vertical sections of the Ni–Sb–Zn ternary system with molar ratio x(Ni):x(Zn) = 1, x(Ni):x(Sb) = 1 and x(Ni) = 0.2, were measured by differential scanning calorimetry (DSC). Predicted isothermal sections at 600 °C and 25 °C were compared with the results of the scanning electron microscope (SEM) with energy dispersive spectrometry (EDS) analysis from this work.
► Review of reported literature.
► Calculated constitutive binary systems.
► Experimentally determined phase transformation temperatures.
► Calculation of several vertical and two horizontal sections, verified by SEM-EDS.
► Determined invariant reaction in Ni–Sb–Zn system.
Journal: Materials Chemistry and Physics - Volume 132, Issues 2–3, 15 February 2012, Pages 402–408