کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1524443 1511837 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A study on structural and optical properties of Mn- and Co-doped SnO2 nanocrystallites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
A study on structural and optical properties of Mn- and Co-doped SnO2 nanocrystallites
چکیده انگلیسی
Pure and transition metal ion (Mn and Co)-doped SnO2 nanoparticles were synthesized using a simple chemical precipitation method. Transition metal ions (Mn and Co) of 1, 3 and 5 mol% were doped in order to study the influence of structural and optical properties. The structural, chemical and optical properties of the samples were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis, and UV-vis spectroscopy techniques. The SnO2 crystallites were found to exhibit tetragonal rutile structure with lattice parameters, revealing that the metal ions get substituted in the SnO2 lattice. It is observed that the peak position (1 1 0) get shifted to lower angles by increasing the dopant concentration. Hence the lattice parameters (a and c) and the cell volume get decreased. The SEM photograph shows that the grain size of pure SnO2 is larger than that of the metal-doped SnO2 indicating grain growth upon doping. TEM photograph revels that by increasing the content of metal ions, average grain size decreased. A significant red shift in the UV absorbing band edge was observed with the increase in the amount of the Mn and Co contents.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 124, Issues 2–3, 1 December 2010, Pages 1046-1050
نویسندگان
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