کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
153567 456532 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Comparison of nickel adsorption from electroplating rinse water by coir pith and modified coir pith
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Comparison of nickel adsorption from electroplating rinse water by coir pith and modified coir pith
چکیده انگلیسی

The coir pith was used as an adsorbent for nickel removal because the coir pith contains high lignin (36%) and cellulose (44%). The optimum condition for nickel removal by coir pith in a batch system was solution pH 4–7, adsorbent dosage of 5% (w/v), an equilibrium contact time of 10 min and a temperature of 30 °C. The nickel adsorption was fitted to the Langmuir and Freundlich isotherms that showed that the maximum value of nickel adsorption (qmax) by coir pith and modified coir pith were 9.5 and 38.9 mg g−1, respectively. Sodium hydroxide increased metal binding site (free O−) of modified coir pith. The mechanism of nickel adsorption by the coconut coir pith was confirmed by elution with sulfuric acid, which implied that it was chemisorption. The evidence showed that lignin and holo-cellulose are the main components in coir pith that played a major role in nickel adsorption. The main functional groups in coir pith that were involved in nickel adsorption were hydroxyl and methoxy groups. It was confirmed by X-ray adsorption spectroscopy (XAS) that the oxidation species of nickel involved in nickel adsorption by coir pith and modified coir pith was Ni(II).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 137, Issue 2, 1 April 2008, Pages 181–188
نویسندگان
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