کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1559346 | 999354 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamic optimization and calculation of the ErCl3–MCl (M=Li,Na,K,Rb,Cs ) systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In this paper, the binary phase diagrams of the ErCl3–MCl (M = Li, Na, K, Rb, Cs) systems were studied by the CALPHAD (CALculation of PHAse Diagram) approach. The modified quasi-chemical model in the pair-approximation for short-range ordering was used to describe the Gibbs energies of the liquid phase in the systems. From measured phase diagram data and experimental thermochemical properties, a series of thermodynamic functions has been optimized based on computer-assisted analysis. A discussion of thermodynamic functions for strong interaction binary systems was undertaken. The results showed that the calculated phase diagrams and optimized thermodynamic parameters are self-consistent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Calphad - Volume 30, Issue 3, September 2006, Pages 301–307
Journal: Calphad - Volume 30, Issue 3, September 2006, Pages 301–307
نویسندگان
Xiangzhen Meng, Yimin Sun, Shunxiang Yuan, Zhisen Ma, Yu Wang, Zhiyu Qiao,