Linear free energy relationship applied to trivalent cations with lanthanum and actinium oxide and hydroxide structure

Linear free energy relationships for trivalent cations with crystalline M2O3 and, M(OH)3 phases of lanthanides and actinides were developed from known thermodynamic properties of the aqueous trivalent cations, modifying the Sverjensky and Molling equation. The linear free energy relationship for trivalent cations is as ΔGf,MvX0=aMvXΔGn,M3+0+bMvX+βMvXrM3+, where the coefficients aMvX, bMvX, and βMvX characterize a particular structural family of MvX, rM3+rM3+ is the ionic radius of M3+ cation, ΔGf,MvX0 is the standard Gibbs free energy of formation of MvX and ΔGn,M3+0 is the standard non-solvation free energy of the cation. The coefficients for the oxide family are: aMvX = 0.2705, bMvX = −1984.75 (kJ/mol), and βMvX = 197.24 (kJ/mol nm). The coefficients for the hydroxide family are: aMvX = 0.1587, bMvX = −1474.09 (kJ/mol), and βMvX = 791.70 (kJ/mol nm).