Precipitation in as-solidified undercooled Ni–Si hypoeutectic alloy: Effect of non-equilibrium solidification

Applying glass fluxing and cyclic superheating, high undercooling up to ∼350 K was achieved for Ni–Si hypoeutectic alloy melt. By isothermally annealing the as-solidified alloy subjected to different undercoolings, precipitation behavior of Ni3Si particle, at 973 K, was systematically studied. It was found that, the nucleation density and the real-time particle size, as well as the precipitation rate, were all increased, provided the sample was solidified subjected to higher undercooling. This was ascribed mainly to the increased solid solubility of Si atom in α-Ni matrix upon non-equilibrium solidification. On this basis, the non-equilibrium dendrite growth upon solidification and the soft impingement prevailing upon solid-state precipitation have been quantitatively connected. As such, the effect of liquid/solid transformation on subsequent precipitation was described.

► The solid solubility of Si atom in α-Ni matrix increased with undercooling in the as-solidified sample.
► The effect of non-equilibrium solidification on precipitation has been theoretically described.
► The nucleation density, the real-time particle size and the precipitation rate are all increased upon annealing.
► The precipitate process can be artificially controlled by modifying the initial melt undercooling and the annealing time.