کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1590792 | 1515465 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new approach to well-defined, stable and site-isolated catalysts
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new concept to circumvent some of the problems that are hindering a rational metallic catalyst development is introduced. Investigation of conventional metal catalysts - which consist of supported metals, metal mixtures or alloys - is handicapped by the presence of a variety of active sites, their possible agglomeration, metal-support interactions as well as segregation of the components. In order to avoid most of the drawbacks, we employ well-defined, ordered and in-situ stable unsupported intermetallic compounds. Knowledge of the chemical bonding in the compounds and the defined neighbourhood of the active sites allows a rational approach to catalysts with excellent selectivity as well as long-term stability. The concept is demonstrated for the intermetallic compound PdGa, which is applied as catalyst for the selective hydrogenation of acetylene to ethylene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Science and Technology of Advanced Materials - Volume 8, Issue 5, July 2007, Pages 420-427
Journal: Science and Technology of Advanced Materials - Volume 8, Issue 5, July 2007, Pages 420-427
نویسندگان
K. Kovnir, M. Armbrüster, D. Teschner, T.V. Venkov, F.C. Jentoft, A. Knop-Gericke, Yu. Grin, R. Schlögl,