کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1604967 | 1516204 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Metal-organic frameworks derived cake-like anatase/rutile mixed phase TiO2 for highly efficient photocatalysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Cake-like anatase/rutile mixed phase TiO2 (A/R TiO2) was successfully prepared through pyrolyzation of metal-organic frameworks MIL-125. Its morphology, structure and photocatalytic performance for degradation of nitrobenzene under UV light irradiation were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, nitrogen adsorption-desorption isotherms, UV-Vis absorption spectroscopy, photocurrent and photoluminescence spectroscopy, respectively. The results show that the cake-like A/R TiO2 exhibits excellent photocatalytic performance with a maximum nitrobenzene degradation rate of 97% and corresponding mineralization rate of 77% at 100Â min under UV light irradiation, which is better than those of cake-like rutile TiO2 and anatase TiO2. The improved photocatalytic performance is ascribed to the reduced electron-hole pair recombination in cake-like A/R TiO2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 690, 5 January 2017, Pages 640-646
Journal: Journal of Alloys and Compounds - Volume 690, 5 January 2017, Pages 640-646
نویسندگان
Jinliang Li, Xingtao Xu, Xinjuan Liu, Wei Qin, Miao Wang, Likun Pan,