کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1606053 1516222 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Continuous preparation of Fe3O4 nanoparticles through Impinging Stream-Rotating Packed Bed reactor and their electrochemistry detection toward heavy metal ions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Continuous preparation of Fe3O4 nanoparticles through Impinging Stream-Rotating Packed Bed reactor and their electrochemistry detection toward heavy metal ions
چکیده انگلیسی


• Fe3O4 nanoparticles were continuous prepared through IS-RPB reactor.
• The Fe3O4 nanoparticles showed selective detection of heavy metal ions.
• It exhibited favorable sensitivity (14.9 μA μM−1) and LOD (0.119 μM) for Pb(II).
• The as-prepared nanoparticles showed favorable potential application.

We reported the continuous preparation and electrochemical behavior toward heavy metal ions of the Fe3O4 nanoparticles (Fe3O4 NPs). This Fe3O4 NPs were fabricated through a novel Impinging Stream-Rotating Packed Bed reactor with a high production rate of 2.23 kg/hour. The as-prepared Fe3O4 NPs were quasi-spherical with a mean diameter of about 10 nm and shown the characteristics of superparamagnetism with the saturated magnetization of 60.5 emu/g. The electrochemical characterization of the as-prepared Fe3O4 NPs toward heavy metal ions were evaluated using square wave anodic stripping voltammetry (SWASV) analysis. The results indicated that the modified electrode could be used to individual detection of Pb(II), Cu(II), Hg(II) and Cd(II). In particular, the modified electrode exhibited the selective detection toward Pb(II) with higher sensitivity of 14.9 μA/μM, while the response to Cu(II), Hg(II) and Cd(II) were negligible. Besides, the modified electrode shown good stability and potential practical applicability in the electrochemical determination of Pb(II). This above results offered a simple method for continuous preparation sensing materials in the application field of electrochemical detection of toxic metal ions through the technology of process intensification.

Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 671, 25 June 2016, Pages 354–359
نویسندگان
, , , ,