کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1608082 | 1516242 | 2015 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Local structure studies of CoFeMnX (X = Si and Ge) Heusler alloys using X-ray absorption spectroscopy Local structure studies of CoFeMnX (X = Si and Ge) Heusler alloys using X-ray absorption spectroscopy](/preview/png/1608082.png)
• EXAFS studies are performed on CoFeMnX (X = Si, Ge).
• Half-metallic CoFeMnGe is found to exist in a well-ordered LiMgPdSn structure.
• Large antisite disorder is observed for spin gapless semiconductor (SGS) CoFeMnSi.
• CoFeMnSi shows a high spin polarization of 64%.
• SGS materials are supposed to be robust against chemical disorder.
In this paper, we report the local structure studies in CoFeMnX (X = Si and Ge) Heusler alloys using extended X-ray absorption fine structure (EXAFS) measurements. CoFeMnGe (CFMG) is found to exist in a well-ordered LiMgPdSn structure, while a large amount of antisite disorder is observed for CoFeMnSi (CFMS). CFMG is half-metallic ferromagnetic in nature, while CFMS is a spin gapless semiconductor (SGS). The presence of well-ordered crystal structure is an essential requirement to obtain high spin polarization in half-metallic materials, while SGS materials are supposed to be robust against chemical disorder. The fact that CFMS shows a high spin polarization of 64% even when having a high degree of disorder confirms that the SGS materials are robust against structural disorder.
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Journal: Journal of Alloys and Compounds - Volume 651, 5 December 2015, Pages 509–513