کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1609139 1516258 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of full concentration-gradient LiNi0.7Co0.1Mn0.2O2 cathode material for lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Synthesis and characterization of full concentration-gradient LiNi0.7Co0.1Mn0.2O2 cathode material for lithium-ion batteries
چکیده انگلیسی
Spherical Ni0.7Co0.1Mn0.2(OH)2 precursor with the content of Ni decreasing gradually from the core to the surface of the particle and the content of Co and Mn increasing was prepared by co-precipitation from sulfate solutions using NaOH and NH4OH as precipitation and complexing agents. Then, well-ordered spherical LiNi0.7Co0.1Mn0.2O2 particles was synthesized by sintering the mixture of as-prepared precursor and LiOH·H2O in flowing oxygen. Their structural and electrochemical properties were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), charge-discharge test, cyclic voltammetry (C-V) method and electrochemical impedance spectroscopy (EIS) test. EDXS results indicated that the concentration of Ni, Co and Mn changed gradually inside out of the particle. The full concentration-gradient (FCG) material had better electrochemical performances compared to homogeneous LiNi0.7Co0.1Mn0.2O2, confirmed by the results of C-V and EIS. The results of charge-discharge tests demonstrated that the FCG-LiNi0.7Co0.1Mn0.2O2 material sintered at 810 °C delivered an initial discharge capacity of 179.1 mA h g−1 at 1 C rate between 2.8 and 4.3 V and more than 94.0% of that was retained after 100 cycles. Besides, it also exhibited excellent rate capability and high voltage and temperature performance, with a high capacity of 155.9 mA h g−1 even at 10 C rate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 635, 25 June 2015, Pages 92-100
نویسندگان
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