کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1609425 | 1516263 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cu-Li2MnSiO4-polyaniline composite hybrids as high performance cathode for lithium batteries
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
We reported the dramatic improvement in electrochemical properties of high capacity orthosilicate, Li2MnSiO4 by conventional sol-gel route. Simple inclusion of metallic Cu and subsequent hybridization with polyaniline (PANI) nanofibers certainly promotes superior electrochemical activity in terms of high reversibility i.e. beyond one electron reaction and cycling stability. First, the Li2MnSiO4 nanoparticles are prepared by adipic acid assisted sol-gel technique at 700 °C under Ar flow by fine tuning the sintering duration. Then, optimization of adipic acid and Cu concentrations are performed based on the mentioned sintering conditions to yield high performance cathode active material. The Cu-Li2MnSiO4-PANI hybrid exhibits the reversible insertion of â¼1.15 and 0.73 mol of Li for first and 50th cycles, respectively. This corresponds to the â¼63% of retention.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 630, 5 May 2015, Pages 292-298
Journal: Journal of Alloys and Compounds - Volume 630, 5 May 2015, Pages 292-298
نویسندگان
Sol-Nip Lee, Seulgi Baek, Samuthirapandian Amaresh, Vanchiappan Aravindan, Kyung Yoon Chung, Byung Won Cho, Won-Sub Yoon, Yun-Sung Lee,