کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1611233 | 1516292 | 2014 | 7 صفحه PDF | دانلود رایگان |
• The interstitial In dopant leads to the local structural perturbations in β-Zn4Sb3.
• The simultaneous increases in α and σ are observed in the In-doped Zn4Sb3 compounds.
• The In dopant plays different doping behaviors by the dopant contents in the samples.
• A maximum ZT of 1.41 at 700 K is achieved for the In-doped Zn4Sb3 compounds.
In-doped β-Zn4Sb3 compounds (Zn4−xInxSb3, 0 ⩽ x ⩽ 0.24) were prepared by melt-quenching and spark plasma sintering technology in the work. The resultant samples were systematically investigated by X-ray diffraction, X-ray photoelectron spectroscopy, differential scanning calorimetry and thermoelectric property measurements. The In dopant was identified to preferentially occupy the interstitial site in β-Zn4Sb3 and led to the local structural perturbations near the 12c Sb2 and 36f Zn1 sites. The Auger parameters of Zn and Sb indicated that the increase in the valence of Zn was attributed to the charge transfer from Zn to In atoms. The binding energies of In 3d5/2 core level showed that the interstitial In dopant was n-type dopant (In3+) in slightly In-doped Zn4−xInxSb3, but acted as acceptor and was p-type dopant (In+) in heavily In-doped ones. The discovery provides a reasonable explanation for the puzzled relation between σ and x for Zn4−xInxSb3. Simultaneously increasing the electrical conductivity and Seebeck coefficient of Zn4−xInxSb3 can be realized through the local structural perturbations. The significantly enhanced power factor and the intrinsic low thermal conductivity resulted in a remarkable increase in the dimensionless figure of merit (ZT). The highest ZT reached 1.41 at 700 K for Zn3.82In0.18Sb3 and increased by 68% compared with that of the undoped β-Zn4Sb3.
Journal: Journal of Alloys and Compounds - Volume 601, 15 July 2014, Pages 50–56