Hydrogen storage properties of pure Mg after the combined processes of ECAP and cold-rolling

• Samples of commercial Mg were processed by ECAP and Cold-Rolling.
• ECAPed cross-section samples were oriented in the (1 0 1) direction.
• Rolled samples were oriented in the (0 0 2) direction favorable to the hydrogenation.
• The best H-sorption results were obtained for rolled with less texture toward (1 0 1).

Commercial Mg was processed by two combined processes: ECAP and cold rolling. Samples were first processed by ECAP for four passes using route Bc, at 300 °C and ram speeds of 3 and 25 mm/min. The ECAPed samples were cold-rolled in several passes. The cold rolled samples, which presented a favorable (0 0 2) texture, presented faster hydrogen absorption kinetic than the just ECAPed samples. No significant changes of desorption temperatures were found. The good results observed in the ECAPed plus cold rolled samples were explained by the acquired preferred orientation and by the increase of defects after cold rolling.