کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1613990 | 1516323 | 2013 | 5 صفحه PDF | دانلود رایگان |
• Magnetic measurements reveal a ferrimagnetic ground state in YMn0.5Cr0.5O3.
• It is suggested that YMn0.5Cr0.5O3 is in a form of double perovskite structure.
• Electrical transport is dominated by the adiabatic small polaron hopping mechanism.
• The double-exchange is unreasonable in the Cr-doped manganites.
Half Cr-doped YMn0.5Cr0.5O3 polycrystalline has been synthesized by means of a standard solid-state reaction method. Powder X-ray diffraction gives evidence that the sample is a single phase of orthorhombic (Pbnm) or monoclinic (P21/c) structure as observed for other doped manganites, rather than the hexagonal structure as YMnO3. Upon cooling, the magnetic susceptibility increases sharply at TC ∼ 75 K, indicating a magnetic ordering occurs. The detailed analysis on the paramagnetic behavior at higher temperatures reveals that the low-temperature order is a ferrimagnetic state. The electrical transport properties show an insulator behavior dominated by the adiabatic small polaron hopping mechanism with high thermal activation energy. The results indicate that the ferromagnetic double exchange (DE) interaction is unreasonable in Cr-doped manganites.
Journal: Journal of Alloys and Compounds - Volume 570, 5 September 2013, Pages 41–45