کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1616088 | 1516369 | 2012 | 4 صفحه PDF | دانلود رایگان |
The crystal structure of Cu2ZnSnS4 (CZTS) thin films fabricated by vapor-phase sulfurization was determined using X-ray anomalous dispersion. High statistic synchrotron radiation X-ray diffraction data were collected from very small amounts of powder. By analyzing the wavelength dependencies of the diffraction peak intensities, the crystal structure was clearly identified as kesterite. Rietveld analysis revealed that the atomic composition deviated from stoichiometric composition, and the compositions were Cu/(Zn + Sn) = 0.97, and Zn/Sn = 1.42.
► Cu2ZnSnS4 thin films as a solar cell material were synthesized.
► The wavelength dependences of the diffraction intensity were measured.
► The crystal structures were clearly identified as kesterite structure for all samples.
► Crystal structure analysis revealed that the atomic compositions were Cu/(Zn + Sn) = 0.97 and Zn/Sn = 1.42 for the sample synthesized using stoichiometric amount of starting materials.
Journal: Journal of Alloys and Compounds - Volume 524, 25 May 2012, Pages 22–25