کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1616321 1516378 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of electronic and magnetic properties of vacuum annealed Cr doped ZnO
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Study of electronic and magnetic properties of vacuum annealed Cr doped ZnO
چکیده انگلیسی

Influence of Cr doping (5%) in ZnO lattice has been investigated in terms of modifications in electronic properties, evolution of defects and exploring their possible relationship with magnetic properties, using SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The Cr doping drives the diamagnetic ZnO host to a paramagnetic state, however, its post annealing in vacuum induces room temperature ferromagnetism (RTFM) in it that disappears by re-heating it in air. The findings infer a reversible ferromagnetic ordering in the Cr doped ZnO matrix. The XPS results indicate trivalent state of the Cr ions in the as-synthesized sample which tend to reduce to bivalency upon its vacuum annealing and also the evolution of oxygen vacancy defects have clearly been observed. The results indicate a close relationship of oxygen vacancies with the induced ferromagnetism.


► Evolution of ferromagnetism in Cr doped ZnO on vacuum annealing.
► The ferromagnetism is a reversible process.
► Electronic properties and ferromagnetism are closely related.
► Oxygen vacancies are very crucial in inducing ferromagnetism.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 515, 25 February 2012, Pages 12–15
نویسندگان
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