کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1616617 | 1005665 | 2012 | 6 صفحه PDF | دانلود رایگان |

Li2FeSiO4/C composites with in situ carbon coating were synthesized via sol–gel method based on acid-catalyzed hydrolysis/condensation of tetraethoxysilane (TEOS) with sucrose and l-ascorbic acid as carbon additives, respectively. As-obtained Li2FeSiO4/C composites prepared with l-ascorbic acid as a carbon additive are composed of nanoparticulate Li2FeSiO4 in an intimate contact with a continuous thin layer of residual carbon and exhibit large specific surface area up to 395.7 m2 g−1. The results indicate that structure of the residual carbon is graphene-rich with obviously lower disordered/graphene (D/G) ratio. These as-obtained Li2FeSiO4/C composites exhibit first discharge capacity of 135.3 mAh g−1 at C/16 and perform cycling stability, which are superior to those of Li2FeSiO4/C composites synthesized with sucrose as a carbon additive.
► Sucrose and l-ascorbic acid as carbon additives.
► Li2FeSiO4/C were obtained under our carbon coating experimental conditions.
► Graphite-rich carbon was formed uniformly when ascorbic acid was employed.
► The composites employing l-ascorbic acid exhibited a large specific surface area.
► Sample using l-ascorbic acid exhibited better rate performance and cycling stability.
Journal: Journal of Alloys and Compounds - Volume 511, Issue 1, 15 January 2012, Pages 101–106