کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1616650 1516381 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Color-tunable and white-light emitting lanthanide complexes based on (CexEuyTb1−x−y)2(BDC)3(H2O)4
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Color-tunable and white-light emitting lanthanide complexes based on (CexEuyTb1−x−y)2(BDC)3(H2O)4
چکیده انگلیسی

Ce3+, Eu3+ and Tb3+ complexes were synthesized through facile and mild approaches with terephthalic acid (H2BDC) as the ligand. Their chemical compositions were determined as (CexEuyTb1−x−y)2(BDC)3(H2O)4 by elemental analysis (EA), Fourier transform infrared (FTIR) spectra and X-ray diffraction (XRD) measurements. Fluorescent properties of the as-synthesized complexes were investigated by changing the molar ratio of Ce3+, Tb3+ and Eu3+ ions, and the optimized ratio of 3.0:2.0:0.15 for Ce3+:Tb3+:Eu3+ in the complex was determined for white-light emission. Tuning on the emitting color was realized by adjusting the ratio among lanthanide ions, indicating the energy transfer process inside the complex. It was found that Tb3+ could sensitize the fluorescence of Eu3+ while its own fluorescence was quenched by the latter ion, and concentration quenching of Ce3+ was also observed. Fairly good thermal stability and oxidation resistance of the as-synthesized complexes were also demonstrated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 510, Issue 1, 5 January 2012, Pages L5–L8
نویسندگان
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