کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1616847 | 1005672 | 2011 | 9 صفحه PDF | دانلود رایگان |

The synthesis of the new compounds RMgSn (R = La–Nd, Sm, Gd–Tm, Lu and Y) has been recently reported. The compounds formed by La and Ce crystallise in the TiNiSi structure type (oP12, Pnma), while from Nd they adopt the CeScSi-type (tI12, I4/mmm); PrMgSn is dimorphic: its high-temperature form (HT) is TiNiSi-type while the low-temperature one (LT) is CeScSi-type.In this paper we now report the results of a neutron diffraction investigation which has been performed in order to refine the crystal as well as the magnetic structures for the RMgSn compounds with R = Ce, Pr, Nd and Tb. All these compounds see at low temperature the establishment of long range magnetic ordering with a predominantly antiferromagnetic interaction; only PrMgSn-HT orders ferromagnetically. These results agree with those from magnetic measurements recently reported.The magnetic structure of CeMgSn is of the amplitude-modulated type, the value of the magnetic propagation vector refined at 2 K is τ = [0, 0.1886(4), 0.3384(8)]. The PrMgSn-HT phase below T = 52 K adopts first a purely ferromagnetic structure, then at about T = 15 K a second magnetic coupling leads to a spin-canted magnetic structure. Both PrMgSn-LT and NdMgSn have the same antiferromagnetic commensurate magnetic structure. The TbMgSn compound below TN = 35 K orders antiferromagnetically with an equal moment cycloidal structure; however a second magnetic transition at a temperature corresponding to TN2 = 65 K is likely also present.
► The room-temperature crystal structure has been refined for five RMgSn phases adopting the CeScSi- and/or the TiNiSi-type structure.
► The magnetic structure has been determined for RMgSn phases with R = Ce, Pr, Nd, Tb.
► The CeScSi-type phases show commensurate (R = Nd, Pr) or incommensurate (R = Tb) antiferromagnetic ordering.
► PrMgSn, high temperature phase, orders first ferromagnetically, then becomes spin-canted.
Journal: Journal of Alloys and Compounds - Volume 509, Issue 41, 13 October 2011, Pages 9724–9732