کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1618737 | 1516383 | 2010 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Partial oxidation of methane over bimetallic copper- and nickel-actinide oxides (Th, U)
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The study of partial oxidation of methane (POM) over bimetallic nickel- or copper-actinide oxides was undertaken. Binary intermetallic compounds of the type AnNi2 (An = Th, U) and ThCu2 were used as precursors and the products (2NiO·UO3, 2NiO·ThO2 and 2CuO·ThO2) characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy and temperature-programmed reduction. The catalysts were active and selective for the conversion of methane to H2 and CO and stable for a period of time of â18 h on stream. The nickel catalysts were more active and selective than the copper catalyst and, under the same conditions, show a catalytic behaviour comparable to that of a platinum commercial catalyst, 5 wt% Pt/Al2O3. The catalytic activity increases when uranium replaces thorium and the selectivity of this type of materials is clearly different from that of single metal oxides and/or mechanical mixtures. The good catalytic behaviour of the bimetallic copper- and nickel-actinide oxides was attributed to an unusual interaction between copper or nickel oxide and the actinide oxide phase as showed by H2-TPR, XPS and Raman analysis of the catalysts before and after reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 497, Issues 1â2, 14 May 2010, Pages 249-258
Journal: Journal of Alloys and Compounds - Volume 497, Issues 1â2, 14 May 2010, Pages 249-258
نویسندگان
Ana C. Ferreira, A.P. Gonçalves, T. Almeida Gasche, A.M. Ferraria, A.M. Botelho do Rego, M.R. Correia, A. Margarida Bola, J.B. Branco,