کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1620448 | 1516387 | 2010 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Combustion synthesis and luminescence investigation of Na3Al2(PO4)3:RE (RE = Ce3+, Eu3+ and Mn2+) phosphor Combustion synthesis and luminescence investigation of Na3Al2(PO4)3:RE (RE = Ce3+, Eu3+ and Mn2+) phosphor](/preview/png/1620448.png)
Rare-earth (Ce3+or Eu3+) or alkali-earth metal (Mn2+) doped Na3Al2(PO4)3 phosphor powder were prepared by a combustion method. Regardless of the dopants, the Na3Al2(PO4)3 was shown to crystallize as hexagonal (rhombohedral) NASICON phase with spheroidal micron sized particles based upon X-ray diffraction (XRD) and scanning electron microscopy (SEM) data. As confirmed by thermogravimetric (TGA) and differential thermal analysis (DTA) data, the powders were stable at high temperatures up to 900 °C. A broad UV emission (with maximum at 328 nm) associated with the 5d → 4f transition of Ce3+ was observed from Na3Al2(PO4)3:Ce3+ while Mn2+ and Eu3+ doping showed stable green and red photoluminescence emission at 515 and 615 nm, respectively. For different molar concentrations of rare-earth/alkali-earth metal dopants, the PL intensity was shown to increase to a certain concentration before quenching occurred at higher concentrations. The structure and optical properties of these phosphors were evaluated.
Journal: Journal of Alloys and Compounds - Volume 492, Issues 1–2, 4 March 2010, Pages 384–388