کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1621161 1005744 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
f↔ff↔f electric dipole transitions; old problems in a new light
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
f↔ff↔f electric dipole transitions; old problems in a new light
چکیده انگلیسی

Very well known difficulties of the theoretical description of the f↔ff↔f electric dipole transitions of lanthanides are addressed in the old language of the standard Judd–Ofelt (J–O) theory, which has been widely applied for more than 45 years. New light is shed on a competitive physical mechanism of these transitions, which is presented to complement the existing J–O model. Possible new solutions are given for the old problems of the negative intensity parameters obtained from the adjusting procedure. An alternative scheme for the reproduction of the hypersensitive transitions is discussed and a theoretical description of highly forbidden transitions 0–0 and 0–1 observed for Eu3+ and Sm2+ ions is presented.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 488, Issue 2, 4 December 2009, Pages 586–590
نویسندگان
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