کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1622065 | 1516392 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Phase transformation of the La0.7Mg0.3Ni2.8Co0.5-H2 system studied by in situ X-ray diffraction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
Phase transformation in the La0.7Mg0.3Ni2.8Co0.5-H2 system along the hydrogen absorption and desorption pressure-composition isotherm was studied using in situ X-ray diffraction. La0.7Mg0.3Ni2.8Co0.5 consisted mainly of the Ce2Ni7-type La3Mg(Ni,Co)14 phase. In hydrogen absorption of the Ce2Ni7-type phase, the hydrogen solid solution and hydride phases coexisted. The solid solution phase transformed to the hydride phase with isotropic expansion of the crystal lattice. In hydrogen desorption, coexistence of the two phases was not observed and the crystal lattice consecutively reduced with reduction of the hydrogen content. Lattice strain in the Ce2Ni7-type phase in hydrogen desorption was higher than that in hydrogen absorption.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 485, Issues 1â2, 19 October 2009, Pages 174-180
Journal: Journal of Alloys and Compounds - Volume 485, Issues 1â2, 19 October 2009, Pages 174-180
نویسندگان
Yujun Chai, Kohta Asano, Kouji Sakaki, Hirotoshi Enoki, Etsuo Akiba,