کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1622065 1516392 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase transformation of the La0.7Mg0.3Ni2.8Co0.5-H2 system studied by in situ X-ray diffraction
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Phase transformation of the La0.7Mg0.3Ni2.8Co0.5-H2 system studied by in situ X-ray diffraction
چکیده انگلیسی
Phase transformation in the La0.7Mg0.3Ni2.8Co0.5-H2 system along the hydrogen absorption and desorption pressure-composition isotherm was studied using in situ X-ray diffraction. La0.7Mg0.3Ni2.8Co0.5 consisted mainly of the Ce2Ni7-type La3Mg(Ni,Co)14 phase. In hydrogen absorption of the Ce2Ni7-type phase, the hydrogen solid solution and hydride phases coexisted. The solid solution phase transformed to the hydride phase with isotropic expansion of the crystal lattice. In hydrogen desorption, coexistence of the two phases was not observed and the crystal lattice consecutively reduced with reduction of the hydrogen content. Lattice strain in the Ce2Ni7-type phase in hydrogen desorption was higher than that in hydrogen absorption.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 485, Issues 1–2, 19 October 2009, Pages 174-180
نویسندگان
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