کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1622098 | 1516392 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structures and electrochemical hydrogen storage characteristics of La0.75âxPrxMg0.25Ni3.2Co0.2Al0.1 (x = 0-0.4) alloys prepared by melt spinning
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
A2B7-type electrode alloys with nominal compositions of La0.75âxPrxMg0.25Ni3.2Co0.2Al0.1 (x = 0, 0.1, 0.2, 0.3, 0.4) were synthesized by melt-spinning technique. The microstructures of the as-cast and spun alloys were characterized by XRD, SEM and TEM. The electrochemical hydrogen storage characteristics of the as-cast and spun alloys were measured. The obtained results show that the as-cast and spun alloys have a multiphase structure which consists of two main phases (La, Mg)Ni3 and LaNi5 as well as a residual phase LaNi2. The substitution of Pr for La leads to an obvious increase of the (La, Mg)Ni3 phase and a decrease of the LaNi5 phase in the alloys. The discharge capacity of the alloys first increases and then decreases with variety of the spinning rate except the (x = 0.4) alloy. The cycle stability of the alloy monotonously rises with increasing spinning rate. When spinning rate rises from 0 (as-cast was defined as spinning rate of 0 m/s) to 20 m/s, the discharge capacity increases from 389.4 (0 m/s) to 393.5 (5 m/s) and then drops to 374 mAh/g (20 m/s) for the (x = 0) alloy, and it mounts up from 392.4 (0 m/s) to 397.9 (5 m/s), after that declines to 383.6 mAh/g (20 m/s) for the (x = 0.1) alloy. The capacity retaining rate after 100 cycles increases from 65.32% to 73.97% for the (x = 0) alloy, and from 73.65% to 86.91% for the (x = 0.1) alloy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 485, Issues 1â2, 19 October 2009, Pages 333-339
Journal: Journal of Alloys and Compounds - Volume 485, Issues 1â2, 19 October 2009, Pages 333-339
نویسندگان
Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Qi Yan, Xin-lin Wang,