کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1623036 | 1516407 | 2009 | 5 صفحه PDF | دانلود رایگان |

In this paper we report a novel Mn3O4 electrode doped with nano-NaBiO3. It is demonstrated that doping with nano-NaBiO3 alters the electrochemical inertia of Mn3O4, converting it into a rechargeable secondary alkaline cathode material that exhibits highly efficient charge/discharge properties. While a pure Mn3O4 electrode can barely maintain a single charge and discharge cycle, the cycling capacity of the Mn3O4 electrode doped with nano-NaBiO3 can reach and become stable at 372 mAh g−1 under 60 mA g−1. The doped cathode can also maintain a cycling capacity of 261 mAh g−1 while holding a 95.3% reversible capacity after 60 cycles at a high rate of 500 mA g−1. Moreover, the experimental results indicate that charging time for an alkaline battery using doped Mn3O4 cathode could possibly shorten to as little as 30 min.
Journal: Journal of Alloys and Compounds - Volume 470, Issues 1–2, 20 February 2009, Pages 75–79