کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1623072 | 1516407 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterizations on the structural and electronic properties of thermal lithiated Li0.33MnO2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A 3 V cathode material for lithium ion batteries, Li0.33MnO2, was synthesized by solid-state reaction. Two Mn crystallographic positions, Mn(1) and Mn(2), were determined by X-ray diffraction analysis. The [Mn(2)O6] octahedron had a lower symmetrical degree than that of [Mn(1)O6], which was attributed to the geometrical effects of the non-symmetrical environment around Mn(2). Li0.33MnO2 delivered a reversible discharge capacity â¼140 mA h gâ1. In situ synchrotron diffraction clearly showed a reversible phase transition of Li0.33MnO2 during electrochemical process. The analysis of X-ray absorption near edge spectroscopy observed the conversion of Mn4+ to Mn3+ with Li+ intercalation into Li0.33MnO2, accompanied by the formation of more severely distorted [MnO6] octahedron.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 470, Issues 1â2, 20 February 2009, Pages 273-277
Journal: Journal of Alloys and Compounds - Volume 470, Issues 1â2, 20 February 2009, Pages 273-277
نویسندگان
Y.J. Wei, H. Ehrenberg, K.B. Kim, C.W. Park, Z.F. Huang, C. Baehtz,