کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1623247 | 1516408 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic effects of pseudo AB2 phases on hydrogen sorption
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The compound GdNi4Mg in its amorphous and crystalline state has been investigated as catalyst for hydrogen sorption of magnesium. Addition of only 0.3Â at.% of catalyst by ball milling resulted in an important improvement of hydrogen sorption kinetics. Optimum milling time has been found to be 5Â h. The amorphous and crystalline GdNi4Mg compounds give almost identical kinetics. Both absorption and desorption have been improved and the kinetics obtained are almost the same as other metal catalysts. No evidences of decomposition during ball milling or hydrogenation have been found so that it should be concluded that the intermetallic itself acts as a catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 469, Issues 1â2, 5 February 2009, Pages 137-141
Journal: Journal of Alloys and Compounds - Volume 469, Issues 1â2, 5 February 2009, Pages 137-141
نویسندگان
J.L. Bobet, Jacques Huot, J.-Gabriel Roquefere, Sebastien Baduel,