کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1623974 | 1516414 | 2008 | 9 صفحه PDF | دانلود رایگان |

The transition metal complex hydride Mg2FeH6 has been successfully synthesized utilizing mechanical milling of a 2Mg–Fe mixture followed by heating at 673 K under 6 MPa of hydrogen pressure, without pressing step. The obtained yield of Mg2FeH6 was about 50%. Hydrogen storage properties of the Mg–Fe–H system, i.e. capacities, absorption/desorption kinetics and thermodynamic parameters, were examined. The pressure-composition isotherm (PCI) measurements of the samples at 548–673 K showed that the alloys possessed good cyclic stability and reversibility. Enthalpies and entropies of decomposition of the Mg–Fe–H system were evaluated by van’t Hoff plots. The absorption/desorption rates at 573 K were very fast in comparison with the reported data. The non-isothermal desorption of hydrogen was found greatly dependent on the thermal history of the sample.
Journal: Journal of Alloys and Compounds - Volume 463, Issues 1–2, 8 September 2008, Pages 134–142