کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1625204 1516426 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and hydrogen storage properties of MgH2 catalysed with La2O3
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Structure and hydrogen storage properties of MgH2 catalysed with La2O3
چکیده انگلیسی
The catalytic effect of the addition of lanthanum oxide (La2O3), in the range 0.5-2.0 mol%, on the hydrogen storage properties of MgH2 prepared by ball milling has been studied. The addition of La2O3 reduces the formation during milling of the metastable orthorhombic γ-MgH2 phase. The desorption rate of samples with 1 and 2 mol% La2O3 comes out to be about 0.010 wt% per second at 573 K under an hydrogen pressure of 0.3 bar, better than for sample with 0.5 mol% La2O3. The presence of LaH3 after hydrogenation/dehydrogenation cycles has been observed in all samples. The sample with 1 mol% of La2O3 gives a lower hysteresis factor compared with sample with 2 mol%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 450, Issues 1–2, 14 February 2008, Pages 310-313
نویسندگان
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