کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1626074 | 1516440 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
EXAFS study of LaNi5 and LaNi4.5Al0.5
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
We report extended X-ray absorption fine structure measurements in the temperature range between 20 and 300Â K at the Ni K absorption edge on LaNi5 and LaNi4.5Al0.5 before and after hydrogen charging. In agreement with previous studies, an increase of the Ni-Ni distance has been found when Ni atoms are partially substituted by Al. For all the samples, the Debye-Waller factors of the Ni-Ni first sub-shells have been fitted with a correlated Debye model plus a temperature independent static disorder, obtaining a Debye temperature dependence on the Al content. Even a small hydrogen content has been found to increase the static contribution to the local disorder around Ni atoms.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 433, Issues 1â2, 16 May 2007, Pages 33-36
Journal: Journal of Alloys and Compounds - Volume 433, Issues 1â2, 16 May 2007, Pages 33-36
نویسندگان
O. Palumbo, C. Castellano, A. Paolone, F. Cordero, R. Cantelli, Y. Nakamura, E. Akiba,