کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1626375 | 1516442 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synthesis, structural characterization and magnetic properties of compounds in the Ln2O3-SrO-NiO-CuO system for Ln = La, Nd, Gd, Dy, Ho and Er
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The synthesis, structural characterization and magnetic properties of compounds in the Ln2O3-SrO-NiO-CuO system for Ln = La, Nd, Gd, Dy, Ho and Er The synthesis, structural characterization and magnetic properties of compounds in the Ln2O3-SrO-NiO-CuO system for Ln = La, Nd, Gd, Dy, Ho and Er](/preview/png/1626375.png)
چکیده انگلیسی
An investigation of the quaternary Ln2O3-SrO-NiO-CuO system has shown that compounds of the formula Ln2âxSrxNi0.8Cu0.2O4âδ (0 < x < 2) with Ln = La, Nd and Gd adopt the K2NiF4-type structure, but a new phase of stoichiometric composition is formed only at x = 1.67 (LnSr5Ni2.4Cu0.6O11) with the smaller lanthanides cations Dy, Ho and Er. All the samples have been prepared at 1150 °C in 1 atm of O2 gas flow using conventional solid state methods. Rietveld refinement of their crystal structures from powder X-ray diffraction data confirms that they adopt the tetragonal structure (space group I4/mmm, Z = 2). Magnetic susceptibility data for Ln2âxSrxNi0.8Cu0.2O4âδ (0 < x < 2) with Ln = La, Nd, Gd, Dy, Ho and Er between 2 and 350 K show Curie-Weiss behavior at higher temperatures characteristic of Ln3+ cation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 431, Issues 1â2, 4 April 2007, Pages 16-22
Journal: Journal of Alloys and Compounds - Volume 431, Issues 1â2, 4 April 2007, Pages 16-22
نویسندگان
Hanèn Chaker, T. Roisnel, M. Ceretti, R. Ben Hassen,