کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1626818 | 1516447 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Boron nonstoichiometry, hardness and oxidation resistance of perovskite-type CeRh3Bx (x = 0-1)
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
We report synthesis of perovskite-type boride CeRh3Bx using the arc melting method. The samples are characterized by powder X-ray diffraction which shows that the crystal structure of CeRh3Bx belongs to the cubic system (space group: Pm3m) in the range of 0 < x â¤Â 1. Furthermore, CeRh3 (x = 0) has the ordered AuCu3-type structure (space group: Pm3m). As a result, CeRh3Bx exists in a wide range of nonstoichiometric boron concentration 0 â¤Â x â¤Â 1 with the space group Pm3m. The lattice parameter, a, changes almost linearly with x, varying from 0.4015(1) nm (x = 0) to 0.4180(1) nm (x = 1.0). The micro-Vickers hardness of the CeRh3Bx for x = 0 (0 at.%B), 0.210 (5 at.%B), 0.444 (10 at.%B), 0.706 (15 at.%B) and 1.0 (20 at.%B) are 2.0 ± 0.1, 4.3 ± 0.2, 1.8 ± 0.2, 5.5 ± 0.1 and 6.5 ± 0.2 GPa, respectively. Thermo-gravimetric analysis was done to study the oxidation resistance of the samples in air. It reveals that oxidation begins at 502 and 513 K for x = 0 and 1.0, respectively. A mixed phase of CeO2 + Rh is identified as an oxidized product for all samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 426, Issues 1â2, 21 December 2006, Pages 304-307
Journal: Journal of Alloys and Compounds - Volume 426, Issues 1â2, 21 December 2006, Pages 304-307
نویسندگان
T. Shishido, M. Oku, J. Ye, S. Okada, K. Kudou, K. Iizumi, Y. Sawada, Y. Ishizawa, A. Nomura, T. Sugawara, K. Obara, R. Sahara, K. Yubuta, H. Kojima, V. Kumar, M. Tanaka, K. Shimamura, S. Oishi, K. Nakajima,