کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1627224 1516453 2006 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Theoretical calculation of thermodynamic data for gold-rare earth alloys with the embedded-atom method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Theoretical calculation of thermodynamic data for gold-rare earth alloys with the embedded-atom method
چکیده انگلیسی
The thermodynamic data, such as the formation enthalpies of disordered solid solutions and intermetallic compounds, and the lattice parameters in the RE-Au (RE = Sc, Y, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Er) systems are calculated with the modified analytical embedded atom method (EAM). This work has been undertaken to investigate systemically in RE-Au alloying energies, and to augment available calorimetric data for enthalpies of formation in support of the development of accurate multicomponent thermodynamics databases for these technologically interesting systems. The accuracy of our calculations is assessed through comparisons with the experimental measurements and the theoretical results from the first-principles VASP as well as Miedema's theory. The composition dependence of the heats of formation for these 10 binary systems is similar, and there is a minimum at 50 at.%Au for REAu (CsCl-type) ordered phase. In all 10 binary systems, the calculated zero-temperature intermetallic formation energies generally agree well with the calorimetric data obtained by the direct reaction synthesis and/or VASP results except for REAu2 (MoSi2-type) phase. For the intermetallic phase, the calculated EAM and VASP zero-temperature lattice parameters agree well with the experimental data at ambient temperature. The largest discrepancy between the EAM calculated lattice parameters and experimental data [K. Fitzner, W.G. Jung, O.J. Kleppa, Metall. Trans. A 22 (1991) 1103 [16]; K. Fitzner, O.J. Kleppa, Metall. Trans. A 24 (1993) 1827 [17]; K. Fitzner, O.J. Kleppa, Metall. Trans. A 25 (1994) 1495 [18]; R. Ferro, G. Borzone, N. Parodi, J. Alloys. Compd. 321 (2001) 248 [19]] is approximately 10-18% for some intermediate phases, such as REAu (CrB-type) and RE3Au4 (Pu3Pd4-type).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 420, Issues 1–2, 31 August 2006, Pages 83-93
نویسندگان
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