کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1646945 | 1517309 | 2012 | 4 صفحه PDF | دانلود رایگان |
We firstly report an efficient and novel method to functionalize graphene with 4-aminophenoxyphthalonitrile and successfully compound them with poly(arylene ether nitrile) (PEN) to prepare nanocomposite films. Fourier transform infrared spectra (FTIR), Raman spectra, and atomic force microscopy (AFM) were employed to examine the surface functionalization of graphene. The resulting PEN nanocomposite exhibited significant increase in dielectric permittivity. For 3 wt.% nitrile functionalized graphene reinforced PEN nanocomposite film, the dielectric constant increased from 3.2 to 17.8 at the frequency of 1 kHz. In addition, the PEN nanocomposite films showed low dielectric loss and good flexibility. This opens a new route to optimize interface structures and improve the comprehensive performances of graphene–polymer nanocomposites.
► Nitrile functionalizzation of graphene(G-CN) was realized and compounded with PEN.
► The dielectric constant of PEN composite films was significantly enhanced.
► PEN nanocomposite films showed low dielectric loss and good flexibility.
Journal: Materials Letters - Volume 78, 1 July 2012, Pages 88–91