کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1647654 1517321 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of heterogeneous oxidation on electrochemical properties of tailored Cu0.4Ru3.4O7 + RuO2 sensing electrode of potentiometric DO sensor
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Effect of heterogeneous oxidation on electrochemical properties of tailored Cu0.4Ru3.4O7 + RuO2 sensing electrode of potentiometric DO sensor
چکیده انگلیسی
Effect of heterogeneous oxidation of the thick-film Cu0.4Ru3.4O7 + RuO2 sensing electrode (SE) of the planar potentiometric dissolved oxygen (DO) sensor on its electrochemical properties has been investigated by field emission beam scanning electron microscopy (FIB-SEM), X-ray photoelectron spectroscopy (XPS), cyclic voltametry (CV) and electrochemical impedance spectroscopy (EIS) techniques. It was found that the most of heterogeneous oxidation has occurred during the first week of SE exposure to the aqueous environment leading to the partial oxidation RuIV to RuIII occurred mostly on the grain boundaries of SE. The presence of the “inner” active surfaces in the bulk of the developed complex oxide SE has been reaffirmed. It was also found that heterogeneous oxidation caused the increase of the Cu 2p peaks intensity on the surface of SE after the water treatment for one month, which has been confirmed by XPS measurement.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 65, Issues 21–22, November 2011, Pages 3219-3222
نویسندگان
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