کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1647667 1517321 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvothermal synthesis of Mn2P2O7 and its application in lithium-ion battery
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Solvothermal synthesis of Mn2P2O7 and its application in lithium-ion battery
چکیده انگلیسی

Manganese pyrophosphate, Mn2P2O7 was synthesized by a simple solvothermal method using Mn metal powder and P2S5 in ethylene glycol medium at 190–220 °C. Morphology and crystalline structure of the products were characterized by X-ray diffraction and scanning electron microscopy. The flower-like microspheres with diameters of about 2–5 μm are composed of a number of nanoplatelets with thickness of 20–40 nm. The effect of reaction temperature and reaction time on the microstructure of Mn2P2O7 was investigated. The samples were used as active anode materials for lithium-ion battery and their electrochemical properties were examined by constant current charge–discharge cycling. The Mn2P2O7 electrodes exhibited initial reversible capacities of 440–330 mAh g− 1 depending on the synthetic conditions. From these results, a possible reaction mechanism of Mn2P2O7 with lithium was proposed.

Figure optionsDownload as PowerPoint slideHighlights
► Manganese pyrophosphate, Mn2P2O7 was synthesized by solvothermal method.
► It exhibits a flower-like morphology formed by agglomeration of many nanoplatelets.
► The electrochemical performance of Mn2P2O7 depends on the microstructure.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 65, Issues 21–22, November 2011, Pages 3265–3268
نویسندگان
, , , , , ,