کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1652083 1007636 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of TiO2 hollow microparticles by spraying water droplets into an organic solution of titanium tetraisopropoxide
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Preparation of TiO2 hollow microparticles by spraying water droplets into an organic solution of titanium tetraisopropoxide
چکیده انگلیسی

Hollow, spherical TiO2 microparticles several tens of micrometers in diameter were prepared by spraying water into an organic phase containing titanium tetraisopropoxide (TTIP) as a titanium source. The rapid hydrolysis of TTIP at the water–oil interface resulted in the formation of a TiO2 shell covering the water droplet. Hexane and cyclohexane were better solvents than isopropanol for fabricating hollow spherical microparticles, suggesting the importance of immiscibility of the solvent with water in this synthesis method. The average particle size increased as the distance from the nozzle to the surface of the TTIP solution was increased. The shell thickness was reduced by the addition of ethanol to the sprayed water droplet. These results demonstrate the controllability of the structure of TiO2 hollow microparticles, including the diameter and the shell thickness.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 61, Issue 2, January 2007, Pages 444–447
نویسندگان
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