کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1656766 | 1517593 | 2016 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Layer-by-layer assembly of silver nanoparticles embedded polyelectrolyte multilayer on magnesium alloy with enhanced antibacterial property
ترجمه فارسی عنوان
مونتاژ لایه ی لایه ی نانو ذرات نقره ی چند لایه پلی یک الکترولیتیک بر روی آلیاژ منیزیم حاوی املاح ضد باکتری
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی
Functionalization of magnesium alloy (Mg alloy) with multiple bioactivities is desired to obtain surfaces with improved biocompatibility and antibacterial property. In this article, an anticorrosive and antimicrobial coating was prepared on Mg alloy surface by layer-by-layer (LbL) assembly of polyelectrolytes. A polycationic copolymer (P(DOP-co-DMAEMA+)) bearing dopamine (DOP) and 2-(methacryloxy)ethyl trimethylammonium chloride (DMAEMA+) was synthesized and deposited on the surface of micro-arc oxidation (MAO) treated Mg alloy substrate as the first layer. The presence of DOP units ensure a strong anchoring on Mg alloy substrate, and the -N+(CH3)3 groups are sources of positive charge, providing electrostatic interaction with polyanion electrolyte. Negatively charged colloidal silver particles were prepared by using dextran sulfate (DS) as a stabilizer to precede chemical reduction by dextrose and served as a polyanion electrolyte. The functional polyelectrolyte multilayered films were obtained by alternating deposition P(DOP-co-DMAEMA+) and DS-stabilized silver colloid (DS-Ag) in a spin-assisted LbL assembly manner. The prepared nanosized silver colloids and functionalized Mg alloy were characterized by ultraviolet-visible (UV-vis) spectroscopy, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Potentiodynamic polarization test confirmed that corrosion resistance of modified Mg alloy significantly increased and the fabricated polyelectrolyte multilayer films showed significant antibacterial activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface and Coatings Technology - Volume 286, 25 January 2016, Pages 103-112
Journal: Surface and Coatings Technology - Volume 286, 25 January 2016, Pages 103-112
نویسندگان
Xiaodan Zhang, Jinhong Yi, Guowei Zhao, Linlin Huang, Guangjun Yan, Yashao Chen, Peng Liu,