The influence of sodium tungstate concentration and anodizing conditions on microarc oxidation (MAO) coatings for aluminum alloy

Microarc oxidation (MAO) coatings on 5052 aluminum alloy are prepared in silicate–hypophosphite electrolytes with sodium tungstate. The effects of sodium tungstate concentrations and current density on the surface morphology, phase composition and properties of the coatings are investigated. With the addition of sodium tungstate in the electrolyte and increase of current density, the final voltage at the microarc discharge process increases. The results also show that the MAO coatings are composed mainly of α-Al2O3 and γ-Al2O3 and the proportion of α-Al2O3 and γ-Al2O3, pore size, surface roughness as well as thickness of the coatings strongly depend on the sodium tungstate concentration and current density. Thus, the hardness, friction coefficient and corrosion resistance of the coatings are significantly influenced by the magnitude of the current density and sodium tungstate concentration. These oxide films on aluminum were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thickness gage, and polarization curves, respectively.

► Deposition of MAO coatings on Al-alloy in silicate-H2PO2 electrolytes with Na2WO4.
► Influence of Na2WO4 concentration and current density on structures and properties.
► The coatings are composed mainly of α-Al2O3 and γ-Al2O3.
► Wear and corrosion behaviors of the coatings are strongly affected by Na2WO4 and current density.