کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
166633 457796 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The thermal dissociation/recombination reaction of hydrogen peroxide H2O2(+M)⇔2OH(+M)H2O2(+M)⇔2OH(+M) III.: Analysis and representation of the temperature and pressure dependence over wide ranges
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The thermal dissociation/recombination reaction of hydrogen peroxide H2O2(+M)⇔2OH(+M)H2O2(+M)⇔2OH(+M) III.: Analysis and representation of the temperature and pressure dependence over wide ranges
چکیده انگلیسی

Experimental rate coefficients for the thermal dissociation H2O2 + (M) → 2OH(+M) and the reverse recombination 2OH(+M) → H2O2(+M) are combined with recent modelling results based on an ab initio potential energy surface. The rate coefficients derived from the complementary experimental and modelling results are represented over wide ranges of temperature and pressure, such as being of interest for practical applications. Limiting low and high pressure rate coefficients as well as detailed and simplified expressions for rate coefficients in the falloff range are given.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Combustion and Flame - Volume 158, Issue 4, April 2011, Pages 594–601
نویسندگان
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