کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1677972 | 1009924 | 2011 | 7 صفحه PDF | دانلود رایگان |

Several techniques are presented for extracting information from atom probe mass spectra by investigating correlations within multiple-ion detector events. Analyses of this kind can provide insights into the origins of noise, the shape of mass peaks, or unexpected anomalies within the spectrum. Data can often be recovered from within the spectrum noise by considering the time-of-flight differences between ions within a multiple event. Correlated ion detection, particularly when associated with shifts in ion energies, may be used to probe the phenomenon of molecular ion dissociation, including the questions of data loss due to ion pile-up or the generation of neutrals in the dissociation process.
Research Highlights
► Multiple-ion detection events may contain information not seen in the mass spectrum.
► Analysis of multiple events can yield information on molecular ion dissociation.
► Neutral species may be generated by dissociation subsequent to field evaporation.
Journal: Ultramicroscopy - Volume 111, Issue 6, May 2011, Pages 473–479