Characterisation of montmorillonites simultaneously modified with an organic dye and an ammonium salt at different dye/salt ratios. Properties of these modified montmorillonites EVA nanocomposites

• A Na+-Mt was modified with two molecules; methylene blue and EHDDMA.
• The ability of these OMt as nanopigments and reinforcing additives in EVA was proved.
• Young's Moduli increased respect to EVA especially at higher loads of MB.
• Thermal stability of the CPN was improved especially due to the presence of MB.
• Hiding power and colouring power in CPN are higher when both molecules are used.

In this work, a sodium montmorillonite (Na+-Mt) was modified with two molecules simultaneously, an organic dye, methylene blue (MB), and ethyl hexadecyl dimethyl ammonium (EHDDMA). The synthesised organo-montmorillonites (OMt) combining different proportions of the two molecules were thoroughly characterised and mixed with ethylene vinyl acetate copolymer (EVA) in order to check the ability of these OMt as pigments and reinforcing additives. The synthesised OMt combining both surfactants, MB and EHDDMA, present higher interlayer distances than those with only MB, which were employed in previous works as nanopigments. When these OMt were incorporated in the EVA matrix, the obtained clay polymer nanocomposites (CPN) showed a high exfoliation degree of the OMt in the polymer, in such a way that at 80% of the cationic exchange capacity (CEC) of the Mt exchanged with EHDDMA, most of the OMt was exfoliated. Moreover, all the obtained CPN showed an increase in the Young's Moduli compared to the EVA reference, and especially those containing higher amounts of MB. The thermal stability of the CPN also increases with the MB content, compared to other CPN including conventional surfactants. The hiding power and colouring power achieved in the CPN are higher even with a much lower load of MB when EHDDMA is exchanged in the Mt.

Figure optionsDownload as PowerPoint slide