کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1695028 | 1519095 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Thermal stability of montmorillonite polyacrylamide and polyacrylate nanocomposites and adsorption of Fe(III) ions Thermal stability of montmorillonite polyacrylamide and polyacrylate nanocomposites and adsorption of Fe(III) ions](/preview/png/1695028.png)
Poly(sodium acrylate), polyacrylamide and their copolymers were introduced into the interlayer spaces of raw montmorillonite (Mt) by in-situ polymerization. The obtained clay polymer nanocomposites (CPN) retained the layered structure. The polymers were intercalated at an intended polymer-to-clay mass ratio of 1:1. Differences in the mechanism of decomposition of samples depended on the type of polymer functional groups. The CPN were tested as adsorbents of Fe3 + ions. The highest adsorption capacity was achieved for samples containing poly(sodium acrylate), which was due to their high swelling capacity and the attraction of iron ions by carboxyl groups.
► Clay mineral/poly(sodium acrylate-co-acrylamide) hydrogel nanocomposites were studied.
► A relatively high amount of raw montmorillonite was introduced to the CPN.
► Effect of polymer composition on the thermal stability of CPN was observed.
► Swelling and adsorption capacity was determined by the hydrogel type.
► High adsorption efficiency in Fe(III) removal was achieved for the studied CPN.
Journal: Applied Clay Science - Volumes 75–76, May 2013, Pages 153–157