کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1696621 | 1011908 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Stability of 4′-substituted monobenzo-15-crown-5-bentonites and its adsorption properties for tetrachloroethane and naphthalene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
ژئوشیمی و پترولوژی
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چکیده انگلیسی
4′-substituted monobenzo-15-crown-5 (SB15C5)-bentonites are prepared from Na-bentonites by 4′-hydroxymethylbenzo-15-crown-5 (HMB15C5), 4′-methylbenzo-15-crown-5 (MB15C5) and benzo-15-crown-5 (B15C5). Their structure characteristics, stability and adsorption properties for naphthalene and 1, 1, 2, 2-Tetrachloethane (TCE) from water are studied. The observed basal spacing increases (ΔdL), ranging from 4 to 8 Ǻ, indicate that SB15C5 can complex with Na+, lying flat or tilting between the layers. Different substituted groups of B15C5 affect the stability of the SB15C5-bentonites. Adsorption isotherms of naphthalene and TCE to SB15C5-bentonites are linear. Thus it could be explained as a partition process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 33, Issue 1, June 2006, Pages 7–12
Journal: Applied Clay Science - Volume 33, Issue 1, June 2006, Pages 7–12
نویسندگان
Liu Yun, Gong Huijuan, Yu Yang, Zou Huixian, Shen Xing, Xian Qiming, Gao Shixiang,