Characterization of polymer-modified cement as a solidification agent for the radwaste

Polymer-modified cement can be produced by partially replacing cement hydrate binders in ordinary Portland cement with polymeric compounds. It is known that the addition of the polymer to the cement paste leads to improved quality, which would be expected to have a high chemical resistance. In order to investigate the application as a solidification agent for the radwaste, polymer-modified cement specimens, by modification with water-based resins, were prepared according to the polymer content from 0% to 30%. The optimized polymer content in the cement pastes was then determined through the compressive strength and the porosity test. Finally, the improved chemical resistance of the polymer-modified cement with the optimized polymer content was evaluated by the thermal cycling, the immersion, and the leaching tests. From the test results, the amount of ions released into the water showed lower values of about 20% at the polymer-modified cement. Especially, a highly improved nuclide diffusivity of Co-60 was observed in the polymer-modified cement.

► Polymer-modified cement (PMC) by modification with water-based resins.
► Determination of the optimized polymer content.
► Evaluation of the improved chemical resistance of the PMC.
► Decrease of the amount of ions released into the demineralized water.
► Highly improved property for the nuclide diffusivity at the Co-60.