Photoionization and third-order susceptibility of a neutral donor in ZnS/InP/ZnSe core/shell spherical quantum dots

The optical properties of a neutral donor in a ZnS/InP/ZnSe core/shell spherical quantum dot have been investigated using the variational method and the compact density-matrix approach. Two parametric potential is chosen as a confinement potential for the shell. Considering the band structure of the system it is assumed that electron is localized in InP shell. It is assumed that the impurity is located in the center of quantum dot core (ZnS). The photoionization cross section as well as the third-order nonlinear optical susceptibility of third harmonic generation has been calculated. The results show that the photoionization and the third-order nonlinear optical susceptibility of a donor in a core/shell spherical quantum dot are strongly affected by the shell thickness. We found that small applied shell thickness will lead to a significant blue shift of the peak positions in the optical spectrum. This kind of structure gives an opportunity to tune and control the photoionization and the third-order nonlinear optical susceptibility of third harmonic generation of a donor impurity by changing the shell thickness.