کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1812445 | 1025616 | 2010 | 5 صفحه PDF | دانلود رایگان |
The electronic structures and magnetic properties of N-doped CeO2 crystals have been investigated by first-principles calculations based on density functional theory with and without U. The results demonstrate a magnetic moment of 1.00μB per N obtained from all schemes. Predictions based on both LSDA and GGA calculations with and without U capture a half-metallic ground state for the N-doped CeO2 system. Several doped configurations calculations within LSDA demonstrate that there exist robust ferromagnetic couplings between these local magnetic moments, which mainly stem from Hund’s rule coupling. The hole-mediated long-range double exchange mechanism is responsible for the predicted ferromagnetism. It turns out that the percolation concentration needed to establish the collective ferromagnetism is at a few percent. However, further test calculations show that a weakly half-metallic ground state is predicted by GGA+U for this system.
Journal: Physica B: Condensed Matter - Volume 405, Issue 23, 1 December 2010, Pages 4858–4862