کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1814864 | 1025656 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Neutron scattering studies of solid-state polymorphism in dimethyl butanol glass formers
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موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
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چکیده انگلیسی
Inelastic incoherent neutron scattering (IINS) and neutron powder diffraction (NPD) studies have been performed for two dimethyl 1-butanols and two dimethyl 2-butanols with CH3 side molecular groups. Low-temperature vibrational density of states confirmed solid-state polymorphism detected by calorimetric methods, i.e., existence of crystalline and ODIC phases for all isomers, orientationally disordered glass for 2,2-DM 1-B and 3,3-DM 2-B, and glass of isotropic phase for 3,3-DM 1-B. Difference in vibrational density of states between glass and the ordered crystal has shown the so-called Boson peak. Influence of the OH group position in the molecules on their vibrational dynamics up to 50 meV is discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 403, Issue 1, 1 January 2008, Pages 109–114
Journal: Physica B: Condensed Matter - Volume 403, Issue 1, 1 January 2008, Pages 109–114
نویسندگان
E. Juszyńska, M. Massalska-Arodź, I. Natkaniec, J. Krawczyk,