کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1816817 1525271 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvent polarity effects on hyperfine couplings of cyclohexadienyl-type radicals
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Solvent polarity effects on hyperfine couplings of cyclohexadienyl-type radicals
چکیده انگلیسی
In this study muon-spin rotation (μSR) serves as a tool for sensitive monitoring of the environment of muoniated radicals in isotropic liquids. A systematic investigation of the behaviour of the hyperfine coupling constants of cyclohexadienyl-type radicals is performed, and it is found that they are in linear dependence on solvent polarity, with certain deviations. These deviations are discussed in detail. It is found that with increasing length of the hydroxyalkyl substituent group the perturbation of the phenyl ring becomes smaller.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volumes 374–375, 31 March 2006, Pages 295-298
نویسندگان
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